" DETERMINATION OF ADULTERANTS IN FOOD"

                   




ABSTRACT

As part of the B.Ed curriculum, i had performed a project for the determination of adulterants in certain food stuffs like chilli powder,pepper, cumin seeds, etc.  The project had turned out to be successful to the best of my knowledge.


INTRODUCTION:

         Adulteration in food is normally present in its most crude form; prohibited substances are either added or partly or wholly substituted. Normally the contamination/adulteration in food is done either for financial gain or due to carelessness and lack in proper hygienic condition of processing, storing, transportation and marketing. This ultimately results that the consumer is either cheated or often become victim of diseases. Such types of adulteration are quite common in developing countries or backward countries. It is equally important for the consumer to know the common adulterants and their effect on health.
           Adulteration is the act of intentionally debasing the quality of food offered for sale either by mixture or substitution of inferior substances or by the removal of some valuable ingredient. In the past few decades adulteration of food has become one of the most serious problems. Consumption of adulterated food causes diseases like cancer, asthma, ulcer, etc. Majority of adulterants used by the shopkeepers are cheap substitutes which are easily available.
          In order to prevent adulteration of food products by dishonest traders, the government has issued ‘The Prevention of Food Adulteration Act’. The Bureau of Indian Standards is the agency in India that provides the certificate of reliability to food manufacturers in India.


SOME COMMON WAYS OF DETECTING FOOD ADULTERATION

1.Papaya seeds are used to adulterate black pepper seeds. Add some of the adulterated sample to glass water. papaya seeds float while pepper seeds do not.
2. Kesari dal is an adulterant in arahar dal and chana dal. Kesari dal pointed and wedge shaped. chana dal/ arahar dal is smooth and round.

3. Starch is used as an adulterant in milk. put few drops of iodine solution in milk . a blue or black colour indicates starch.
4. Old used spices are often mix with spices sold as fresh. Smell the spice . no or less smell indicates the adulteration
5. Cheap edible oil in vanaspati. Add a solution of washing soda to vanaspati and shake well. If froth appears on top, cheap oil has been added to vanaspati.
6. Artificial dye in tea leaves. Put tea leaves or moistened blotting paper. Artificial colour leaves will impart colour to blotting paper


NEED AND SIGNIFICANCE OF THE STUDY

We are very fortunate to be born a country which is blessed with rich soil, diversified climate, many rivers and the great Himalayas where almost all varieties of fruits, vegetables and cereals, etc. can be grown. In ancient times, the land was in abundance, the supply of food was more than the demand and people used fresh food materials in most natural form.
           The population spurt in our country has given rise to unemployment and poverty. The demand for food has increased & our country has to import food grains, oil etc. from other countries. This shortage of food and ignorance of consumers is the main cause for adulteration of foodstuffs by the unscrupulous traders. It has become so common that the consumers have to run from pillars to pillars to get a foodstuff which is not adulterated.
      
       The consumers are not aware of hazards of adulteration and pay heavily for consuming adulterated food. If the consumer knows the ways and means to check the commodities of daily use, they can save themselves and their families from this mind-boggling problem.           In the past few decades, adulteration of food has become one of the serious problems. Consumption of adulterated food causes serious diseases like cancer, diarrhoea, asthma, ulcers, etc. Majority of fats, oils and butter are paraffin wax, castor oil and hydrocarbons. Red chilli powder is mixed with brick powder and pepper is mixed with dried papaya seeds. These adulterants can be easily identified by simple chemical tests.
          Several agencies have been set up by the Government of India to remove adulterants from food stuffs.
         AGMARK - acronym for agricultural marketing....this organisation certifies food products for their quality. Its objective is to promote the Grading and Standardisation of agricultural and allied commodities.


OBJECTIVE:

To study some of the common food adulterants present in different food stuffs.


Causes of Food Adulteration:

Let us be clear that food adulteration in India under the law includes both willful adulteration of food and "substandard" foods which do not conform to the prescribed food standards but are not done intentionally. Taking an overall view of all types of food adulteration, three major underlying causes could be identified:
i. Inadequate availability of food to meet the demands of the consumer prompting the unscrupulous food traders to use any means to stretch the supply to earn more money.
ii. The more important reason is the basic dishonesty of the food traders and an urge to make quick and easy money. In fact, this urge to make money in an unscrupulous manner is possibly the basic reason for the majority of crimes committed in the modern day society, be it theft, burglary, bank looting or murder. This dishonesty to earn easy and quick money is not only restricted to the food traders who commit crime of food adulteration but can also apply with equal force to the law enforcer who might make an alliance with the food trader with most disastrous results.
iii. There are significant numbers of cases of food adulteration committed by small
traders due to their ignorance about the standards they are expected to maintain. It is true that all food standards after they are developed are circulated by government notification for the knowledge of all traders; but it is equally true that there is an abysmal gap between the traders and the law enforcers, especially when they are small and medium traders e.g. the street corner food sellers.

Food safety knowledge & practices

          Food safety is defined as food that is free from all hazards, whether chronic or acute, that may make food injurious to health of the consumer (Krueger R. 1998). However, the term ‗‗safe food‘‘ represents different ideals to different audiences (World Health Organization; 2003). Unlike in the West, in the Indian context improper cooking and cross-contamination may not be perceived as major food safety concerns; Research in other parts of the world suggests that many people‘s stance on food safety issues changes depending on their mood or the last thing they have read or seen (Elmi M.2004, FSA, 2000).
        Epidemiologic surveillance summaries of foodborne diseases clearly indicate that consumer behaviours such as ingestion of raw/undercooked foods and poor hygienic practices are important contributors to outbreaks of food borne diseases (Patil et al., 2004). Unusan (2007) reported that people of all ages seem to think they know how to handle food safely, but their self-reported food-handling


behaviors do not support this confidence. A review of the consumer food safety literature indicates many gaps that have an impact on food borne diseases at home (Vitas, 2005; Hillers et al., 2003; Jay, Comar, 1999b; Kendall et al., 2004; Kennedy et al., 2005; Li-Cohen, 2002; Redmond, 2003; Unusan, 2007; Yang, 2000).
         The growing concern about pesticide residues was obvious in some areas, which to a large extent is fueled by recent and extensive media coverage of the controversy about pesticide residues in carbonated beverages.( Subba Rao, 2007; Mago C, 2009; CNN, 2003) .


EXPERIMENTAL METHODS:

EXPERIMENT NO:1
    To detect the presence of adulterants in oil and butter.

 REQUIREMENTS

    Test-tube, acetic anhydride, conc. HNO3.
PROCEDURE

    Common adulterants present in ghee and oil are paraffin wax, hydrocarbons and argemone oil. These are detected as follows :

(i)                Adulteration of paraffin wax and hydrocarbon in vegetable ghee
    Heat small amount of vegetable ghee with acetic anhydride. Droplets of oil floating on the surface of unused acetic anhydride indicates the presence of wax or hydrocarbons.

(ii)             Adulteration of argemone oil in edible oils
    To small amount of oil in a test-tube, add few drops of conc. HNO3 and shake. Appearance of red colour in the acid layer indicates presence of argemone oil.



 EXPERIMENT NO:2

   To test the presence of the vanaspati ghee in a given sample of ghee and butter.

REQUIREMENTS
   Test tubes, desi-ghee, diluted HCl, butter, water, and little sugar


PROCEDURE
1. Detection of Vanaspati:
    A small amount {0.5gm} of ghee was taken in a test tube. The tube was heated gently and a little sugar and HCl was added to it. The test tube was shaken well for five minute. Presence of pink color showed the presence of vanaspati ghee.


EXPERIMENT NO:3
   To test the adulteration of dyes in fats.

REQUIREMENTS
   A sample of fat, conc. Sulphuric acid, acetic acid, test tube.

PROCEDURE
   1ml of fat was heated with as mixture of 1ml of conc. Sulphuric acid &4ml of acetic acid. Appearance of red colour indicated the presence of dye in fat.

EXPERIMENT NO:4

   To detect the presence of adulterants in sugar

 REQUIREMENTS

   Test-tubes, dil. HCl


PROCEDURE

 Sugar is usually contaminated with washing soda and other insoluble substances which are detected as follows :

(i)                Adulteration of various insoluble substances in sugar
    Take small amount of sugar in a test-tube and shake it with little water. Pure sugar dissolves in water but insoluble impurities do not dissolve.

(ii)             Adulteration of chalk powder, washing soda in sugar
   To small amount of sugar in a test-tube, add few drops of dil. HCl. Brisk effervescence of CO2 shows the presence of chalk powder or washing soda in the given sample of sugar.

EXPERIMENT NO:5

   To detect the presence of adulterants in samples of chilli powder, turmeric powder and pepper

 REQUIREMENTS

   Test-tubes, conc. HCl, dil. HNO3, KI solution

PROCEDURE

   Common adulterants present in chilli powder and pepper are red coloured lead salts and dried papaya seeds respectively. They are detected as follows :

(i)                Adulteration of red lead salts in chilli powder
    To a sample of chilli powder, add dil. HNO3. Filter the solution and add 2 drops of potassium iodide solution to the filtrate. Yellow ppt. indicates the presence of lead salts in chilli powder.


  1. (i)                Adulteration of brick powder in red chilli powder

    Add small amount of given red chilli powder in beaker containing water. Brick powder settles at the bottom while pure chilli powder floats over water.

  1. (ii)             Adulteration of dried papaya seeds in pepper

   Add small amount of sample of pepper to a beaker containing water and stir with a glass rod. Dried papaya seeds being lighter float over water while pure pepper settles at the bottom.


EXPERIMENT NO:6

   To Detect the presence of given sample of turmeric powder.

REQUIREMENTS

    Test tube, dil. HCl, turmeric powder, dil.nitric acid, conc.HCl

PROCEDURE
(i)      Detection of chalk powder
                   A small amount of given sample was taken in a test tube & about ml of dil. HCl   was    added to it. No effervescence indicates the absence of chalk powder in the sample.

(ii)    Adulteration of yellow lead salts to turmeric powder

      To a sample of turmeric powder add conc. HCl. Appearance of magenta colour shows the presence of yellow oxides of lead in turmeric powder.


OBSERVATIONS AND RESULTS




 CONCLUSION


           Selection of wholesome and non-adulterated food is essential for daily life to make sure that such foods do not cause any health hazard. It is not possible to ensure wholesome food only on visual examination when the toxic contaminants are present in ppm level. However, visual examination of the food before purchase makes sure to ensure absence of insects, visual fungus, foreign matters, etc. Therefore, due care taken by the consumer at the time of purchase of food after thoroughly examining can be of great help. Secondly, label declaration on packed food is very important for knowing the ingredients and nutritional value. It also helps in checking the freshness of the food and the period of best before use. The consumer should avoid taking food from an unhygienic place and food being prepared under unhygienic conditions. Such types of food may cause various diseases. Consumption of cut fruits being sold in unhygienic conditions should be avoided. It is always better to buy certified food from reputed shop.

      The increasing number of food producers and the outstanding amounts of imported food stuffs enables the producers to mislead and cheat consumers. To differentiate of those who take advantage of legal rules from the once who commit food adulteration is very difficult. The consciousness of consumers has become very crucial. However, how can we expect consequent behaviour from them regarding controversial issues emerging day by day? In addition, ignorance and unfair market behaviours is endangering consumer health. So we need sanctions and judicial penalties with adequate restating force to halt this process.




REFERENCES
1.     www.scribd.com
3.     Detection of common food adulterants -  Bruce, Edwin Morris,1866
4.     Simple methods for detecting food adulteration [SPCK] - Bower,John A, 1895
5.     Detection of fraud and protection of health – Byron, Marcus Lafayette, 1826-1903



  

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